The first air conditioners and refrigerators employed toxic or flammable gases, such as ammonia, methyl chloride, or propane, that could result in fatal accidents when they leaked. Thomas Midgley, Jr. created the first non-flammable, non-toxic chlorofluorocarbon gas, Freon, in 1928. The name is a trademark name owned by DuPont for any chlorofluorocarbon (CFC), hydrochlorofluorocarbon (HCFC), or hydrofluorocarbon (HFC) refrigerant. The refrigerant names include a number indicating the molecular composition (e.g., R-11, R-12, R-22, R-134A). The blend most used in direct-expansion home and building comfort cooling is an HCFC known as chlorodifluoromethane (R-22).

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